Smirk (?), v. i. [imp. & p. p.Smirked (?); p. pr. & vb. n.Smirking.] [OE. smirken, ASS. smercian, smearcian; cf. MHG. smieren, smielen, to smile. See Smile, v. i.] To smile in an affected or conceited manner; to smile with affected complaisance; to simper.
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Webster's Dictionary 1913
Webster's Revised Unabridged Dictionary, C. & G. Merriam Co., 1913.